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InfluxDB
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I wrote a python library for directly generating GCode when I was working at a university lab that needed more direct control over their very high end 3D printers. You can check it out here:
https://github.com/jminardi/mecode
Its been a few years since I have worked on it but from what I understand the lab members are still using it.
With fullcontroll.xyz you can edit every point and its properties like speed, extrusion values or non-planar coords.
I've been developing a similar add-on for Blender called nozzleboss. https://github.com/Heinz-Loepmeier/nozzleboss