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Have you tried this? https://github.com/carlk3/no-OS-FatFS-SD-SPI-RPi-Pico
I have managed to interface to an SD card as a block device, no file system. I was able to play audio that I dumped to the card. The project is here: https://github.com/blippy/rpi/tree/master/pico/sdcard It is not feature-complete (it doesn't write to cards, and only supports version 2 cards), but hey, it is at least a proof-if-concept that it is doable.
There is https://github.com/raspberrypi/pico-extras/tree/master/src/rp2_common/pico_sd_card which is SDIO based, and works for reading/writing sectors, but very bare bones prototype atm.